Inorganic Chemistry
Article
Catalysts for Selective Hydrogenation of Nitro Compounds. Nano
Lett. 2018, 18 (6), 3785−3791.
CONCLUSIONS
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In summary, low-cost, magnetically recyclable, and high-
hydrogenation activity metal catalyst Fe/Fe C NPs encapsu-
(
4) Byun, S.; Song, Y.; Kim, B. M. Heterogenized Bimetallic Pd-Pt-
3
Fe O Nanoflakes as Extremely Robust, Magnetically Recyclable
3 4
lated in N-doped carbon tubes were designed and obtained
from pyrolysis of MIL-88d and melamine. The considerable
catalytic performance of functionalized nitro compounds under
mild conditions is attributed to the core−shell structure of the
NCTs, which could overwhelmingly decrease the extent of
Catalysts for Chemoselective Nitroarene Reduction. ACS Appl. Mater.
Interfaces 2016, 8 (23), 14637−14647.
(5) Nandi, S.; Patel, P.; Khan, N. U.; Biradar, A. V.; Kureshy, R. I.
Nitrogen-rich graphitic-carbon stabilized cobalt nanoparticles for
chemoselective hydrogenation of nitroarenes at milder conditions.
Inorg. Chem. Front. 2018, 5 (4), 806−813.
leaching and prevent the aggregation of Fe NPs. The Fe/
6
(6) She, W.; Qi, T. Q. J.; Cui, M. X.; Yan, P. F.; Ng, S. W.; Li, W. Z.;
Fe C@N CT-900-1 catalyst is easily retrieved with a magnet.
3
Li, G. M. High Catalytic Performance of a CeO -Supported Ni
2
The catalyst could be reused for more than six cycles without
any decrease in activity. Our work reveals a novel path for the
design and construction of uniform dispersed metal/metal
carbide embedded in nitrogen-doped carbon tubes with
improved performance with respect to the catalytic hydro-
genation reactions.
Catalyst for Hydrogenation of Nitroarenes, Fabricated via Coordina-
tion-Assisted Strategy. ACS Appl. Mater. Interfaces 2018, 10 (17),
1
(
2
4698−14707.
7) Grove, D. E. 5% Pd/C-Precise but Vague. Platinum Met. Rev.
002, 46 (2), 92.
(8) Vivancos, A.; Beller, M.; Albrecht, M. NHC-Based Iridium
Catalysts for Hydrogenation and Dehydrogenation of N-Heteroarenes
in Water under Mild Conditions. ACS Catal. 2018, 8 (1), 17−21.
ASSOCIATED CONTENT
Supporting Information
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(9) Meemken, F.; Baiker, A. Recent Progress in Heterogeneous
*
S
Asymmetric Hydrogenation of C = O and C = C Bonds on Supported
Noble Metal Catalysts. Chem. Rev. 2017, 117 (17), 11522−11569.
(10) Patil, B. R.; Bari, A. H.; Pinjari, D. V.; Pandit, A. B. Intrinsic
Kinetics of Three-Phase Slurry Hydrogenation of o-Nitrocardanol to
o-Aminocardanol over Raney Nickel Catalyst. Ind. Eng. Chem. Res.
Experimental Section (including Figure S1), character-
ization (Figures S2−S10 and Tables S1−S4), gas
2
(
017, 56 (39), 11034−11041.
11) Snider, J. L.; Streibel, V.; Hubert, M. A.; Choksi, T. S.; Valle, E.;
Upham, D. C.; Schumann, J.; Duyar, M. S.; Gallo, A.; Abild-Pedersen,
F.; Jaramillo, T. F. Revealing the Synergy between Oxide and Alloy
Phases on the Erformance of Bimetallic In-Pd Catalysts for CO2
Hydrogenation to Methanol. ACS Catal. 2019, 9, 3399−3412.
AUTHOR INFORMATION
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(12) Zegkinoglou, I.; Pielsticker, L.; Han, Z.-K.; Divins, N.; Kordus,
D.; Chen, Y.-T.; Escudero, C.; Perez-Dieste, V.; Zhu, B.; Gao, Y.;
Roldan Cuenya, B. Surface Segregation in CuNi Nanoparticle
*
*
*
Catalysts during CO Hydrogenation: the Role of CO in the Reactant
2
Mixture. J. Phys. Chem. C 2019, 123 (13), 8421−8428.
(13) Chen, F.; Topf, C.; Radnik, J.; Kreyenschulte, C.; Lund, H.;
ORCID
Schneider, M.; Surkus, A. E.; He, L.; Junge, K.; Beller, M. Stable and
Inert Cobalt Catalysts for Highly Selective and Practical Hydro-
genation of C N and C = O Bonds. J. Am. Chem. Soc. 2016, 138 (28),
8781−8788.
(14) Hu, M. Z.; Zhao, S.; Liu, S. J.; Chen, C.; Chen, W. X.; Zhu, W.;
Notes
Liang, C.; Cheong, W. C.; Wang, Y.; Yu, Y.; Peng, Q.; Zhou, K. B.; Li,
J.; Li, Y. D. MOF-Confined Sub-2 nm Atomically Ordered
Intermetallic PdZn Nanoparticles as High-Performance Catalysts for
Selective Hydrogenation of Acetylene. Adv. Mater. 2018, 30 (33),
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
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1
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801878.
Our work was supported by the NSFC (21701002, 21401004,
and 21571092), the Natural Science Foundation of Anhui
Province (1508085QB36), the Open Foundation of Anhui
Laboratory of Molecule-based Materials (fzj19005), and the
National Creative Plan of Students (201810370443).
15) Fu, F. Y.; Wang, C. L.; Wang, Q.; Martinez-Villacorta, A. M.;
Escobar, A.; Chong, H. B.; Wang, X.; Moya, S.; Salmon, L.; Fouquet,
E.; Ruiz, J.; Astruc, D. Highly Selective and Sharp Volcano-type
Synergistic Ni Pt@ZIF-8-Catalyzed Hydrogen Evolution from
2
Ammonia Borane Hydrolysis. J. Am. Chem. Soc. 2018, 140 (31),
1
(
0034−10042.
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