Synlett p. 467 - 468 (1997)
Update date:2022-08-11
Topics:
Ohkuma, Takeshi
Ikehira, Hideyuki
Ikariya, Takao
Noyori, Ryoji
The Ru(II)-BINAP-1,2-diphenylethylenediamine combined catalyst system effects asymmetric hydrogenation of certain cyclic enones in 2-propanol containing KOH with a substrate/catalyst molar ratio of 250 to 2500. The hydrogenation occurs selectively at the C=O function with excellent enantio- or diastereoselectivity.
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