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Plea sC eh de om ni oc ta al dS j uc si et nm c ae rgins
DOI: 10.1039/C7SC00713B
Journal Name
ARTICLE
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8
a) J. L. Gong, H. R. Yue, Y. J. Zhao, S. Zhao, L. Zhao, J. Lv, S. P.
Wang, X. B. Ma, J. Am. Chem. Soc., 2012, 134, 13922-13925;
b) H. R. Yue, Y. J. Zhao, S. Zhao, B. Wang, X. B. Ma, J. L. Gong,
Conclusions
In conclusion, the original organosilica nanotubes containing
iridium-bipyridine complexes IrCp*-BPy-NT or Ir(cod)-BPy-NT
were respectively obtained by the post-synthetic metalation of
Nat. Commun., 2013, 4, 2339-2345; c) C. X. Zhang, W. C. Zhu,
S. R. Li, G. W. Wu, X. B. Ma, X. Wang, J. L. Gong, Chem.
Commun., 2013, 49, 9383-9385.
a) C. Copéret, D. P. Estes, K. Larmier, K. Searles, Chem. Rev.,
BPy-NT with Ir complex precursors [IrCp*Cl(µ-Cl)]
2
or
[
Ir(cod)(OMe)] The molecular heterogeneous Ir-based
2
.
2
016, 116, 8463-8505; b) R. J. Comito, K. J. Fritzsching, B. J.
Sundell, K. Schmidt-Rohr, M. Dinca, J. Am. Chem. Soc., 2016,
38, 10232-10237; c) J. D. Pelletier, J. M. Basset, Acc. Chem.
catalysts were successfully applied in the heterogeneous
catalytic C-H oxidation and C-H borylation reactions, which
showed high catalytic activity and durability owing to the
effective suppression of the iridium-bipyridine complex
aggregation as well as the fast transport in short nanotubes.
1
Res., 2016, 49, 664-677; d) S. A. Burgess, A. Kassie, S. A.
Baranowski, K. J. Fritzsching, K. Schmidt-Rohr, C. M. Brown,
C. R. Wade, J. Am. Chem. Soc., 2016, 138, 1780-1783.
M. P. Conley, C. Copéret, C. Thieuleux, ACS Catal., 2014, 4,
1458-1469.
9
1
The characterizations for Ir-BPy
x
-NT after the reactions
0 B. Li, F. Li, S. Y. Bai, Z. J. Wang, L. C. Sun, Q. H. Yang, C. Li,
Energy Environ. Sci., 2012, , 8229-8233.
1 F. Wu, Y. Feng, C. W. Jones, ACS Catal., 2014,
indicated the nature of the active species was molecular
structure, not iridium oxide or iridium nanoparticles. These
results demonstrate the great potential of BPy-NT with short
length as a heterogeneous solid support and an integration
platform for the heterogeneous catalysis systems of organic
transformations.
5
1
1
4, 1365-1375.
2 E. Karakhanov, A. Maximov, Y. Kardasheva, V. Semernina, A.
Zolotukhina, A. Ivanov, G. Abbott, E. Rosenberg, V.
Vinokurov, ACS Appl. Mater. Interfaces, 2014, 6, 8807-8816.
3 C. Copéret, J. M. Basset, Adv. Synth. Catal., 2007, 349, 78-92.
4 D. P. Estes, G. Siddiqi, F. Allouche, K. V. Kovtunov, O. E.
Safonova, A. L. Trigub, I. V. Koptyug, C. Coperet, J. Am. Chem.
Soc., 2016. 138, 14987-14997.
5 H. Noh, Y. Cui, A. W. Peters, D. R. Pahls, M. A. Ortuno, N. A.
Vermeulen, C. J. Cramer, L. Gagliardi, J. T. Hupp, O. K. Farha,
J. Am. Chem. Soc., 2016. 138, 14720-14726.
6 D. T. Genna, L. Y. Pfund, D. C. Samblanet, A. G. Wong-Foy, A.
J. Matzger, M. S. Sanford, ACS Catal., 2016, 6, 3569-3574.
1
1
Acknowledgements
1
1
We thank Dr. Shinji Inagaki in Toyota R&D Labs for the fruitful
discussions, Dr. Zhenchao Zhao in Dalian University of
Technology for solid NMR measurement. We also thank
instrumental analysis centre of Tianjin University for assistance 17 a) T. Maschmeyer, F. Rey, G. Sankar, J. M. Thomas, Nature,
with SEM, TEM, MASS, UV/vis, XPS, NMR analysis. We
acknowledge the National Science Foundation of China
1995, 378, 159-162; b) H. Li, H. Yin, F. Zhang, H. Li, Y. Huo, Y.
Lu, Environ. Sci. Technol., 2009, 43, 188-194; c) C. Li, Catal.
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(
21525626, 21276191, U1662109), and the Program of
Introducing Talents of Discipline to Universities (B06006), and
the Natural Science Foundation of Tianjin City 19 a) C. Wang, Z. Xie, K. E. deKrafft, W. Lin, J. Am. Chem. Soc.,
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8 T. Tagata, M. Nishida, A. Nishida, Tetrahedron Lett., 2009, 50
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,
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(16JCQNJC06200) for financial support.
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W. Lin, J. Am. Chem. Soc., 2015, 137, 2665-2673; c) C. Wang,
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