Catalysis Letters p. 2383 - 2389 (2019)
Update date:2022-08-11
Topics:
Liu, Shiwei
Han, Jing
Wu, Qiong
Bian, Bing
Li, Lu
Yu, Shitao
Song, Jie
Zhang, Cong
Ragauskas, Arthur J.
Abstract: Cyclohexanone is an important intermediate in the manufacture of polyamides in chemical industry, but direct selective hydrogenation of phenol to cyclohexanone under mild conditions is a challenge. Hydrogenation of phenol to cyclohexanone has been investigated in the presence of the composite catalytic system of Pd/C-heteropoly acid. 100% conversion of phenol and 93.6% selectivity of cyclohexanone were achieved within 3?h under 80?°C and 1.0?MPa hydrogen pressure. It has been found that a synergetic effect of Pd/C and heteropoly acid enhanced the catalytic performance of the composite catalytic system which suppressed the hydrogenation of cyclohexanone to cyclohexanol. Graphic Abstract: [Figure not available: see fulltext.].
View MoreChangzhou Chenqiang Chemical Co., Ltd
website:http://www.cq-chem.com
Contact:+86-519-88902455
Address:Shanghuang Town, Liyang City
Contact:+86-571-28186845
Address:Room 1224,Eastcom Mansion,398 Wensan Road,Hangzhou,310013 China
Shandong Xinke Petrochemical Co., Ltd.
Contact:+86-546-7277016
Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.
Contact:86-022-89880739
Address:10B, Pan China International Center, No. 931 YingKou Road, TangGu, Tianjin, China, 300451
Changzhou Medi-tech Bioscientific Co., Ltd.
Contact:86-519-83246372
Address:Number 115 Menghedadao Road, Changzhou, Jiangsu, China
Doi:10.1021/ja01135a503
(1952)Doi:10.1021/jacs.5b03382
(2015)Doi:10.1021/jo01093a607
(1959)Doi:10.1039/a809042d
(1999)Doi:10.1002/(SICI)1096-9063(199904)55:4<434::AID-PS909>3.0.CO;2-Z
(1999)Doi:10.1039/d0ra06934e
(2020)