10.1002/anie.202005589
Angewandte Chemie International Edition
RESEARCH ARTICLE
García Sancho, R. Moreno-Tost, J. A. Cecilia, P. Maireles-Torres, Int. J.
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responsible for the formation of the gem-diols-type species. The
surface gem-diols-type species shows high reactivity towards
cyclohexanol, which leads to a facile formation of iso-propanol
and cyclohexanone via the MPVO process. Although the direct
carbon-to-carbon hydrogen transfer has been well-recognized
as the key step in the MPVO reaction, our experiments and DFT
calculations demonstrate that the gem-diols-type species can
serve as an active intermediate, providing an energy-favorable
route for the direct hydrogen transfer reaction. The results
presented herein will be helpful for understanding the reaction of
ketone catalyzed by Lewis acid zeolite and the carbonyl
chemistry.
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Acknowledgements
This work was supported by the National Natural Science
Foundation of China (Grants 21872170, U1932218,
22061130202, 21733013, 91745111), Key projects of
international partnership plan for foreign cooperation
(112942KYSB20180009), key program for frontier science of the
Chinese Academy of Sciences (QYZDB-SSW-SLH027) and
Hubei Provincial Natural Science Foundation (2017CFA032).
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Conflict of interest
The authors declare no conflict of interest.
Keywords: Ketone • Intermediate • Zeolites • Carbonyl group •
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