5288
S. Malla Reddy et al. / Tetrahedron Letters 47 (2006) 5285–5288
Table 3. Asymmetric dihydroxylation of trans-stilbene with recycled
polysulfone–MC-OsO4
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a
Run
Time (min)
Yieldb (%)
eec (%)
1
2
3
4
5
25
30
30
30
30
94
94
92
90
86
96
97
96
97
97
a Asymmetric dihydroxylation of trans-stilbene was carried out with
(DHQD)2PHAL, and H2O–acetone–CH3CN (1:1:1) as solvent in the
presence of NMO.
b Isolated yields after column chromatography.
c Enantiomeric excess was determined by chiral HPLC.
3.52–3.67 (2H, m). EIMS (m/z): 138 (M+), 107, 106, 79,
57, and 42.
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chemicals.