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Chemical Science
Page 6 of 7
COMMUNICATION
Journal Name
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J. Am. Chem. Soc., 2012, 134, 2934.
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4 M. A. Affan and P. G. Jessop, Inorg. Chem., 2017, 56, 7301-
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DOI: 10.1039/C9SC03242H
transmission electron microscopy (TEM) images were obtained
by JEOL-2100F. X-ray photoelectron spectroscopy (XPS) were
collected on an ESCALab220i-XL electron spectrometer from
VG Scientific at a pressure of 3× 10 mbar using 300 W Al-Kα
radiation. The binding energies (BEs) were referenced to the C
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s line at 284.8 eV from adventitious carbon. The X-ray
absorption data at the Pd K-edge of the samples were
recorded at room temperature in fluorescence mode with
6 U. Jayarathne, N. Hazari and W. H. Bernskoetter, ACS Catal.,
2
018, 8, 1338.
silicon drift fluorescence detector at beam line BL14W1 of the 17 X. J. Cui, X. C. Dai, Y. Zhang, Y. Q. Deng and F, Shi. Chem. Sci.,
Shanghai Synchrotron Radiation Facility (SSRF), China. The
2014, 5, 649.
electron storage ring was operated at 3.5 GeV. Data processing 18 K. Beydoun, G. Ghattas, K. Thenert, J. Klankermayer and W.
Leitner, Angew. Chem. Int. Ed., 2014, 53, 11010.
9 K. Kon, S. M. A. H. Siddiki, W. Onodera and K.-i. Shimizu, Chem.
was performed using the program ATHENA. The electrospray
ionization mass spectrometry (ESI-MS) data (in both the
negative and positive modes) was collected by Bruker 9.4T
Solarix instrument model.
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Eur. J., 2014, 20, 6264.
0 I. Sorribes, J. R. Cabrero-Antonino, C. Vicent, K. Junge and M.
Beller, J. Am. Chem. Soc., 2015, 137, 13580.
1 C. Fang, C. L. Lu, M. H. Liu, Y. L. Zhu, Y. Fu and B. L. Lin, ACS
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Conflicts of interest
2 H. Yang and F. C. Thyrion, Int. J. Chem. Kinet., 1994, 26, 309.
There are no conflicts to declare.
23 S. A. Gamzaeva, P. S. Mamedova, K. M. Allakhverdieva, G. K.
Velieva, M. A. Akhundova and M. A. Allakhverdiev, Russ. J. Appl.
Chem., 2009, 82, 1577.
2
4 K. H. Chen, G. L. Shi, W. D. Zhang, H. R. Li and C. M. Wang, J.
Am. Chem. Soc., 2016, 138, 14198.
5 Z. R. Zhang, J. L. Song and B. X. Han, Chem. Rev., 2017, 117,
Acknowledge
This work was financially supported by National Key Research
and Development Program of China (2017YFA0403102,
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834.
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017YFA0403003), Natural Science Foundation of China 26 A. Weilhard, M. I. Qadir, V. Sans and J. Dupont, ACS Catal.,
(
21890761, 21533011, 21773266), Chinese Academy of
2018, 8, 1628.
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7 Y. F. Zhao, Z. Z. Yang, B. Yu, H. Y. Zhang, H. J. Xu, L. D. Hao, B. X.
Han and Z. M. Liu, Chem. Sci., 2015, 6, 2297.
8 X. X. Sang, J. L. Zhang, J. F. Xiang, J. Cui, L. R. Zheng, J. Zhang, Z.
H. Wu, Z. H. Li, G. Mo, Y. Xu, J. L. Song, C. C. Liu, X. N. Tan, T.
Luo, B. X. Zhang and B. X. Han, Nat. Commun., 2017, 8, 175.
9 M. Y. Liu, Z. R. Zhang, H. Z. Liu, Z. B. Xie, Q. Q. Mei and B. X.
Han, Sci. Adv., 2018, 4, eaas9319.
Sciences (QYZDY-SSW-SLH013-2), and Beijing Municipal
Science & Technology Commission (Z181100004218004).
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