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ChemComm
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COMMUNICATION
Journal Name
DOI: 10.1039/C9CC02172H
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Fig. 4 2D 1H/13C correlation solid-state NMR spectra of (a) 1 and (b) 1g. (c) 1H-63Cu
RESPDOR build up curve, showing the strength of 1H-63Cu heteronuclear dipolar
interactions for aromatic and CH3 protons in 1 (solid line) and 1g (dashed line). (d)
Monolith of 1g prepared by melt-quench.
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gentle cooling. The CP glass maintains the coordination
environment characterized by X-ray adsorption, and partial
metal ligand connectivity similar to the crystal structure. The
balance of iconicity, symmetry of metal ion/ligand, and tailored
intermolecular interactions in CP are the key to observed stable
liquid state. The present results contribute to share the
information how to synthesize the melting CP/MOF crystals and
expand the library of available metals centres.
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The work was supported by the Japan Society of the
Promotion of Science (JSPS) for a Grant-in-Aid for Scientific Re-
search (B) (JP18H02032) from the Ministry of Education,
Culture, Sports, Science and Technology, Japan, and Strategic
International Collaborative Research Program (SICORP) and
Adaptable and Seamless Technology Transfer Program through
Target-driven R&D (A-STEP) from the Japan Science and
Technology, Japan. We acknowledge Aichi Synchrotron
Radiation Center BL5S1 beamline for XAS, and SPring-8 BL02B2
beamline for XRPD.
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Conflicts of interest
There are no conflicts to declare.
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4 | J. Name., 2012, 00, 1-3
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