Journal of Organometallic Chemistry p. C83 - C85 (1987)
Update date:2022-08-11
Topics:
Denise, B.
Navarre, D.
Rudler, H.
Whereas μ-alkylidene complex Fe2<μ-CH2(CO)8> reacts with CO and ROH to give mainly the ester CH3CO2R, the μ-alkylidene complex Pd2<μ-CH2(PPh2CH2PPh2>I2 gives malonate CH2(CO2R)2 with a selectivity of 88percent.
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