Journal of Physical Chemistry p. 41 - 49 (1982)
Update date:2022-08-29
Topics:
Brenner, D. M.
Both ethyl vinyl ether (EVE) and dihydrofuran (DHF) dissociate by two reaction channels which differ by ca. 25 kcal mol-1 in activation energies.In DHF, the branching ratio between these channels produced by IR-multiphoton-induced dissociation shows no power dependence, by contrast to previous work with EVE.In view of the similarity of the Arrhenius activation parameters in the two systems, this is surprising.Therefore, a comparison of peak-power dependence of the branching ratio in the two systems has been studied at hνCO2 = 1076 cm-1 where the average energy absorbed is the same in both molecules.Results on the power dependence of branching ratio and yield suggest that differences in absorption coefficients (pumping rates) in the quasicontinuum may account for the differences in power dependence.
View MoreHEZE KINGVOLT CHEMICAL CO., LTD
Contact:86-573-82118911
Address:Juancheng Industry Park
Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.
Contact:86-532-88250866
Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China
Jiaxing Trustworthy Import And Export Co.,Ltd
Contact:+86-573-82030555
Address:Room 1202, Unit B, Charming plaza,No.1558 East Zhongshan Road , Jiaxing City, Zhejiang Province, China.
Alpha(shijiazhuang) Chemical Co., Ltd
Contact:+86-311-85652680
Address:Shijiazhuang City ,Hebei Province China
Shanghai Yuking Water Soluble Material Tech Co., Ltd
Contact:86-21-68286299
Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
Doi:10.1002/bkcs.11252
(2017)Doi:10.1039/c6gc00341a
(2016)Doi:10.1021/j100886a516
(1965)Doi:10.1039/c4ra13338b
(2015)Doi:10.1021/ja00825a047
(1974)Doi:10.1021/op049878r
(2004)