Journal of the Chemical Society - Faraday Transactions p. 3247 - 3252 (1990)
Update date:2022-08-17
Topics:
Bennett, John E.
The kinetics of reactions of t-butylperoxyl radicals in aqueous solution have been measured using electron paramagnetic resonance, ultraviolet absorption spectroscopy and gas chromatography.The rate constants for the overall self-reaction, the separate terminating and non-terminating reactions are very similar to those observed in non-polar solvents and the gas phase.The t-butoxy radicals, formed by the non-terminating reaction, can either undergo scission, which leads to methylperoxyl radicals, or react with further t-butyl hydroperoxide to regenerate t-butylperoxy radicals.The cross-termination reaction between methylperoxyl and t-butylperoxyl radicals is an important route in the overall termination sequence.The propagation reaction occurs significantly only at high concentrations of t-butyl hydroperoxide, (
Contact:86-512-87182056
Address:No.128 Fangzhou Rd, Suzhou Industrial Park, China, 215125, China
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD
Contact:29-63685658 63685359
Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
Contact:+86-535-8888888
Address:No.161 Haishi Rd.
Evergreen Chemical Industry Ltd.
Contact:86-553-4918210
Address:6#2-602 Wanhaobailing
Tengzhou Runlong Fragrance Co., Ltd.
website:http://www.tzrunlong.com/
Contact:0086-15665710862
Address:No. 78, Fushan Road, Biomedical Industrial Park, Dawu Town, Tengzhou, Shandong, 277514 China
Doi:10.1039/c5ta01861g
(2015)Doi:10.3987/COM-17-13714
(2017)Doi:10.1007/BF00903236
(1980)Doi:10.1021/jacs.6b05498
(2016)Doi:10.1039/b822328a
(2009)Doi:10.1021/ja804816a
(2008)