Chemistry of Heterocyclic Compounds p. 646 - 650 (1998)
Update date:2022-08-17
Topics:
Poskonin
Badovskaya
The characteristics of the oxidation of furfural in the hydrogen peroxide-VOSO4-sodium acetate system and the composition of the products were studied. The principal stages of the reaction occur at pH ~7. The direction of the reaction is very different from the process in an acidic medium, where β-formylacrylic and maleic acids are mainly formed. The main oxidation products in the acetate buffer solution in the presence of VOSO4 are succinic and β-formylpropionic acids and 2(5H)-furanone; without the catalyst the main product is 2-furancarboxylic acid. A mechanism is proposed for the transformations of furfural in the investigated system. 1998 Plenum Publishing Corporation.
View MoreContact:+86-27-85733560
Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
Zhejiang kehong chemical co., ltd
Contact:0086-575-85522000
Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073
website:http://www.finetechnology-ind.com
Contact:86-27-87465837
Address:wuhan
Wuhan Sunrise Pharmaceutical Technology Co., Ltd
Contact:+86-27-83314682
Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
Shenzhen Feiming Science and Technology Co,. Ltd
Contact:+86-755-85232577
Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
Doi:10.1021/jo01328a051
(1979)Doi:10.1021/jacs.5b01391
(2015)Doi:10.1080/00397911.2021.1873383
(2021)Doi:10.1039/CT8844500198
(1884)Doi:10.1016/S0040-4039(00)81430-6
(1983)Doi:10.1248/cpb.48.163
(2000)