Russian Journal of General Chemistry p. 1930 - 1934 (2005)
Update date:2022-08-11
Topics:
Kirilin
Belova
Knyazev
Lega
Petrov
Chernyshev
Reactions of organosilyl isocyanates with hydrazine, 1,1-dimethylhydrazine, and 1-methyl-1-[2-(1-methylhydrazino)ethyl]hydrazine provide a facile synthetic route to urea and previously unknown semicarbazides. Quantum chemistry was used to study the structure and electronic properties of (chloromethyl)- dimethylsilyl isocyanate and (chlorodimethylsilyl)methyl isocyanate and to obtain the thermodynamic parameters of their isomerization.
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