Journal of Organometallic Chemistry p. 69 - 76 (1990)
Update date:2022-08-18
Topics:
Zhang, Yiping
Liao, Shijian
Xu, Yun
Hydrogenation of 1-hexene was catalyzed by titanium complexes allowed to react in situ with active alkali metal hydrides.Under normal temperature and pressure, a maximum turnover number of 2270 min-1 was obtained using Cp2TiCl2/NaH as catalyst, while a high turnover of 9290 in 80 min was achieved using a less active but more stable catalyst
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