Journal of Organometallic Chemistry p. 35 - 40 (1997)
Update date:2022-08-11
Topics:
Frediani, Piero
Bianchi, Mario
Salvini, Antonella
Carluccio, Luciano C.
Rosi, Luca
Ruthenium carbonyl acetato complexes containing bipyridines or phenantrolines ligands are tested as catalysts in the hydroformylation of hex-1-ene in homogeneous phase. These catalysts are active also in solutions containing water and the selectivity to aldehyde is high. Only a moderate hydrogenation of the alkene occurs. The regioselectivity to the linear aldehyde reaches 85.7% when using the mononuclear complex containing 4,7-dmphen as ligand. In the course of the reaction the starting olefm is largely isomerized.
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