ACS Catalysis p. 2802 - 2810 (2016)
Update date:2022-08-24
Topics:
Mormul, Jaroslaw
Breitenfeld, Jan
Trapp, Oliver
Paciello, Rocco
Schaub, Thomas
Hofmann, Peter
A method for the synthesis of the industrially relevant monomers adipic acid, 1,6-hexanediol (HDO), and 1,6-hexanediamine (HMD) via isomerizing hydroformylation of 1,3-butadiene is described. The aldehyde intermediates are protected in situ as acetals to avoid hydrogenation to pentanal. Adipic aldehyde diacetal is obtained in good yields, and the first examples for the conversion toward adipic acid, 1,6-hexanediol, and 1,6-hexanediamine are shown.
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