FIRST EXAMPLE OF BORIRANE SYNTHESIS BY α-OLEFINS REACTION WITH BCL3·SME2
1523
[S(CH3)2], 24.55 (С2), 68.50 (С4О), 117.16, 120.27,
127.90, 161.10. 11B NMR spectrum, δ, ppm: 2.67.
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2-Benzyl-1-chloroborirane (22). Yield 40%. Н
NMR spectrum, δ, ppm: –0.38 br.m (1Н, Н3А), 0.62
br.m (1Н, Н3B), 1.20–1.29 br.m [7Н, Н2, S(CH3)2],
vol. 23, p. 454.
4
2.48 m (2H, Н2 ), 7.04–7.17 m (5Нarom). 13С NMR
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spectrum, δ, ppm: 17.79 (С3, W1/2 30.8 Hz), 18.50
(SMe2), 24.30 (С2), 37.71 (С4), 125.30, 127.60,
127.80, 144.10. 11B NMR spectrum, δ, ppm: 2.84.
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The study was carried out under the financial
support of the Russian Foundation for Basic Research
(grant no. 14-03-00295) and of a stipend of the
President of Russian Federation for young scientists
and postgraduate students (SP-2783.2013.1).
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RUSSIAN JOURNAL OF ORGANIC CHEMISTRY Vol. 51 No. 11 2015