RSC Advances
Paper
¨
precursor and MIL-101(Cr) as support. TEM conrms the
S. K. Garlapati, S. Dasgupta, E. Redel, L. Sun and C. Woll, J.
presence of the Pd NPs and their high dispersion within the
Mater. Chem. A, 2016, 4, 12739–12747.
cages of MIL-101(Cr) without affecting the MOF structure, 15 J. Liu, W. Zhou, J. Liu, I. Howard, G. Kilibarda, S. Schlabach,
crystallinity and porosity compared to pristine MIL-101(Cr). The
high catalytic activity and excellent selectivity of BED was ach-
ieved for the prepared Pd@MIL-101(Cr) in the partial hydroge-
D. Coupry, M. Addicoat, S. Yoneda, Y. Tsutsui, T. Sakurai,
S. Seki, Z. Wang, P. Lindemann, E. Redel, T. Heine and
¨
C. Woll, Angew. Chem., Int. Ed., 2015, 54, 7441–7445.
nation of BYD, due to the high dispersion and well conned Pd 16 J. Li, Q. L. Zhu and Q. Xu, Chem. Commun., 2014, 50, 5899–
NPs within MIL-101(Cr), which suppresses further hydrogena- 5901.
tion and isomerization of BED. The recyclability of the Pd@MIL- 17 M. Meilikhov, K. Yusenko, D. Esken, S. Turner, G. Van
101(Cr) hetero-catalyst were also evaluated, and has shown that
they possess excellent stability. Our results have revealed that
Tendeloo and R. A. Fischer, Eur. J. Inorg. Chem., 2010,
2010, 3701–3714.
¨
the hybrid Pd@MIL-101(Cr) is a promising hetero-catalyst for 18 M. Sabo, A. Henschel, H. Frode, E. Klemm and S. Kaskel, J.
BYD hydrogenation towards industrial applications. Further Mater. Chem., 2007, 17, 3827.
improvements of the selectivity of BYD hydrogenation by opti- 19 A. Aijaz, A. Karkamkar, Y. J. Choi, N. Tsumori, E. Ronnebro,
mizing the Pd@MIL-101(Cr) catalyst and developments of other
metal NPs@MOFs hetero-catalysts are undergoing in our lab.
T. Autrey, H. Shioyama and Q. Xu, J. Am. Chem. Soc., 2012,
134, 13926–13929.
¨
20 F. Schroder, D. Esken, M. Cokoja, M. W. E. v. d. Berg,
O. I. Lebedev, G. V. Tendeloo, B. Walaszek, G. Buntkowsky,
H.-H. Limbach, B. Chaudret and R. A. Fischer, J. Am.
Chem. Soc., 2008, 130, 6119–6130.
Acknowledgements
We gratefully acknowledge the nancial support provided by
the National Natural Science Foundation of China (21673032, 21 D. Esken, S. Turner, O. I. Lebedev, G. V. Tendeloo and
21573031 and 21428301) and the Fundamental Research Funds R. A. Fischer, Chem. Mater., 2010, 22, 6393–6401.
for the Central Universities (DUT15ZD106 and DUT15RC(4)09). 22 G. Lu, S. Li, Z. Guo, O. K. Farha, B. G. Hauser, X. Qi, Y. Wang,
X. Wang, S. Han, X. Liu, J. S. DuChene, H. Zhang, Q. Zhang,
X. Chen, J. Ma, S. C. Loo, W. D. Wei, Y. Yang, J. T. Hupp and
F. Huo, Nat. Chem., 2012, 4, 310–316.
References
1 M. Eddaoudi, D. F. Sava, J. F. Eubank, K. Adil and 23 S. Hermes, M. K. Schroter, R. Schmid, L. Khodeir,
V. Guillerm, Chem. Soc. Rev., 2015, 44, 228–249.
2 Z. Zhang, L. Zhang, L. Wojtas, P. Nugent, M. Eddaoudi and
M. J. Zaworotko, J. Am. Chem. Soc., 2012, 134, 924–927.
3 O. M. Yaghi, M. O'Keeffe, N. W. Ockwig, H. K. Chae,
M. Eddaoudi and J. Kim, Nature, 2003, 423, 705–714.
4 H. Furukawa, K. E. Cordova, M. O'Keeffe and O. M. Yaghi,
Science, 2013, 341, 1230444–1230455.
M. Muhler, A. Tissler, R. W. Fischer and R. A. Fischer,
Angew. Chem., Int. Ed., 2005, 44, 6237–6241.
24 M. Zhang, J. Guan, B. Zhang, D. Su, C. T. Williams and
C. Liang, Catal. Lett., 2012, 142, 313–318.
25 J. Liu, L. Chen, H. Cui, J. Zhang, L. Zhang and C. Y. Su, Chem.
Soc. Rev., 2014, 43, 6011–6061.
26 V. I. Isaeva, O. P. Tkachenko, E. V. Afonina, L. M. Kozlova,
¨
5 A. Cadiau, K. Adil, P. M. Bhatt, Y. Belmabkhout and
M. Eddaoudi, Science, 2016, 353, 137–140.
G. I. Kapustin, W. Grunert, S. E. Solov’eva, I. S. Antipin
and L. M. Kustov, Microporous Mesoporous Mater., 2013,
¨
6 O. Shekhah, J. Liu, R. A. Fischer and C. Woll, Chem. Soc. Rev.,
166, 167–175.
2011, 40, 1081–1106.
27 K. Weissermel and H.-J. Arpe, Ind. Org. Chem., John Wiley &
7 O. K. Farha, I. Eryazici, N. C. Jeong, B. G. Hauser,
Sons, 2008.
C. E. Wilmer, A. A. Sarjeant, R. Q. Snurr, S. T. Nguyen, 28 H. Lindlar, Helv. Chim. Acta, 1952, 35, 446–450.
A. O. Yazaydin and J. T. Hupp, J. Am. Chem. Soc., 2012, 134, 29 M. Telkar, C. Rode, V. Rane and R. Chaudhari, Catal.
15016–15021.
8 L. J. Murray, M. Dinca and J. R. Long, Chem. Soc. Rev., 2009, 30 I. T. Duncanson, I. W. Sutherland, B. Cullen, S. D. Jackson
38, 1294–1314.
and D. Lennon, Catal. Lett., 2005, 103, 195–199.
9 M. D. Allendorf, C. A. Bauer, R. K. Bhakta and R. J. T. Houk, 31 H. Li, Y. Zhao, C. Gao, Y. Wang, Z. Sun and X. Liang, Chem.
Chem. Soc. Rev., 2009, 38, 1330–1352. Eng. J., 2012, 181–182, 501–507.
10 N. Yanai, K. Kitayama, Y. Hijikata, H. Sato, R. Matsuda, 32 C. Berguerand, I. Yuranov, F. Cardenas-Lizana, T. Yuranova
Commun., 2005, 6, 725–730.
´
Y. Kubota, M. Takata, M. Mizuno, T. Uemura and
and L. Kiwi-Minsker, J. Phys. Chem. C, 2014, 118, 12250–
S. Kitagawa, Nat. Mater., 2011, 10, 787–793.
12259.
11 P. Horcajada, R. Gref, T. Baati, P. Allan, G. Maurin and 33 H.-U. Blaser, A. Baiker and R. Prins, Heterogeneous catalysis
P. Couvreur, Chem. Rev., 2012, 112, 1232–1268.
and ne chemicals IV, Elsevier, 1997.
12 M. Zhao, K. Deng, L. He, Y. Liu, G. Li, H. Zhao and Z. Tang, J. 34 M. Telkar, C. Rode, V. Rane, R. Jaganathan and
Am. Chem. Soc., 2014, 136, 1738–1741. R. Chaudhari, Appl. Catal., A, 2001, 216, 13–22.
13 L. Ye, J. Liu, Y. Gao, C. Gong, M. Addicoat, T. Heine, C. Woll 35 M. Zhang, Y. Yang, C. Li, Q. Liu, C. T. Williams and C. Liang,
and L. Sun, J. Mater. Chem. A, 2016, 4, 15320–15326. Catal. Sci. Technol., 2014, 4, 329–332.
14 J. Liu, W. Zhou, J. Liu, Y. Fujimori, T. Higashino, H. Imahori, 36 I. Luz, C. Rosler, K. Epp, F. X. Llabres i Xamena and
¨
¨
´
X. Jiang, J. Zhao, T. Sakurai, Y. Hattori, W. Matsuda, S. Seki,
R. A. Fischer, Eur. J. Inorg. Chem., 2015, 2015, 3904–3912.
1632 | RSC Adv., 2017, 7, 1626–1633
This journal is © The Royal Society of Chemistry 2017