Green Chemistry
Paper
of weakly chemisorbed H species which were desorbed around 15 P. Yan, J. Mensah, A. Adesina, E. Kennedy and
150 °C. Also, the Ni/Escott and Ni/NZ exhibit a higher HDO M. Stockenhuber, Appl. Catal., B, 2020, 267, 118690.
activity compared to Ni/BEA and Ni/MOR in the HDO of 16 C. Zhao and J. A. Lercher, Angew. Chem., 2012, 124, 6037.
anisole due to their high hydrogenation activity. The high con- 17 X. Liu, W. An, C. H. Turner and D. E. Resasco, J. Catal.,
centration of strong Brønsted acid sites and large number of
surface Ni sites in Ni/BEA enhanced the transalkylation of 18 Y. Zheng, N. Zhao and J. Chen, Appl. Catal., B, 2019, 250,
anisole to phenol and hydrogenolysis of phenol to benzene, 280.
followed by the hydrogenation of benzene to cyclohexane, 19 H. Wang, M. Feng and B. Yang, Green Chem., 2017, 19,
2018, 359, 272.
leading to a relatively improved HDO activity compared to its
hydrogenation activity.
1668.
20 X. Xu, E. Jiang, Z. Li and Y. Sun, Fuel, 2018, 221, 440.
21 D. P. Gamliel, B. P. Baillie, E. Augustine, J. Hall,
G. M. Bollas and J. A. Valla, Microporous Mesoporous Mater.,
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22 S. Xu, A. Zheng, Y. Wei, J. Chen, J. Li, Y. Chu, M. Zhang,
Q. Wang, Y. Zhou, J. Wang, F. Deng and Z. Liu, Angew.
Chem., 2013, 125, 11778.
Conflicts of interest
There are no conflicts to declare.
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Acknowledgements
Authors thanks the Zeolite Australia Limited for providing the
natural zeolites. Funding from the Australian Research
Council is gratefully acknowledged. Authors thank the
Electron Microscope and X-ray Unit of the University of
Newcastle for the use of their facilities.
27 O. Akpolat, G. Gunduz, F. Ozkan and Nu. Besün, Appl.
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