Tetrahedron Letters p. 5477 - 5480 (1984)
Update date:2022-08-30
Topics:
McKinney, Michael A.
Kremer, Kathleen G.
Aicher, Thomas
Raction of the title spiroactivated cyclopropane(2) with pyridine in acetonitrile yields a zwitterionic addition product.The reaction is reversible which provides conditions under which rates and equilibria constants can be obtained along with the derived activation and thermodynamic parameters of reaction.An extended Bronsted treatment affords a βnuc value for the reaction of 2 with substituted pyridines.
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