Synthesis p. 356 - 365 (1997)
Update date:2022-08-17
Topics:
Miko?ajczyk, Marian
Zurawiński, Remigiusz
Kie?basin?ski, Piotr
Wieczorek, Micha? W.
B?aszczyk, Jaros?aw
Majzner, Wies?aw R.
trans-3-Carboxy-2-diethoxyphosphorylcyclopentanone (11), a key precursor of sarkomycin 1, has been synthesized in the rhodium(II) acetate promoted cyclization of diethyl 1-diazo-2-oxohept-6-enephosphonate (9), followed by transformation of the 3-vinyl moi
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