Journal of the Chemical Society, Dalton Transactions p. 55 - 58 (1980)
Update date:2022-08-11
Topics:
Kurtev, Kurti
Ribola, Dominique
Jones, Richard A.
Cole-Hamilton, David J.
Wilkinson, Geoffrey
Complexes of ruthenium(II) and rhodium(I) containing tris(2-pyridyl)phosphine
are described, examples being RuHCl
3 and RhCl
2.In certain cases, as in these, the nitrogen atom of one of the 2-pyridyl groups can act as a donor to give a P,N chelate ligand.In the presence of an excess of P(py)3 and at low CO + H2 (1 : 1) pressures, the complex RhH(CO)(PPh3)
2 acts as a catalyst for the selective hydroformylation of hex-1-ene to n-heptanal.
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