Russian Chemical Bulletin p. 1866 - 1869 (1996)
Update date:2022-08-11
Topics:
Kolesnichenko
Sharikova
Murzabekova
Markova
Slivinskii
Approaches to increasing the selectivity of water-soluble catalytic systems based on RhCl3 and polycation in hydroformylation of hex-1-ene were studied. The introduction of a long-chain alkyl radical into the polycation or the use of a higher fatty acid anion results in an increase in the selectivity of the catalytic system at pH > 7 with respect to n-aldehyde to 60 %. This effect is presumably associated with the suppression of isomerization processes due to steric hindrances.
View MoreSpringchem New Material Technology Co.,Limited
website:http://www.spring-chem.com
Contact:86-21-62885108
Address:602B, Building 1, No. 641, Tianshan Road
Contact:0512-62706911
Address:No.289 Yinzhong South Road Wuzhong Economic Development District,Suzhou,China
Landz International Company Ltd.
Contact:0086-21-58891610
Address:985 Dongfang Road, Pudong, Shanghai 200122 China
Jinan Jinguilin Chemical Co.,Ltd
Contact:+86-531-81188412
Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan
Chengdu Daoerji Medical Technology Co., Ltd
Contact:86-28-85528891
Address:Southwest University For Nationalities,Wuhou District,Chengdu City,Sichuan Province
Doi:10.1002/chem.201604512
(2017)Doi:10.1021/ja206408q
(2011)Doi:10.1016/j.cclet.2018.12.002
(2019)Doi:10.1021/jacs.9b02909
(2019)Doi:10.1021/acs.biochem.5b01331
(2016)Doi:10.1016/j.ejmech.2019.04.074
(2019)