Tetrahedron Letters p. 75 - 76 (1986)
Update date:2022-08-11
Topics:
Sakurai, Hideki
Ando, Masatomo
Kawada, Nobuo
Sato, Kazuhiko
Hosomi, Akira
Oxidative cleavage of carbon-silicon bond of organosilanes with trimethylamine-N-oxide is achieved under mild conditions.The reaction occurs chemoselectively irrespective of the presence of amino and thio groups to give formally anti-Markovnikov hydration product of 1-alkenes and 1-alkynes via hydrosilylation.
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