Metal-Anion Coordination and Linker-Anion Hydrogen Bonding
can be described as packing of square grids. Besides the
metal-ligand coordination during the MOF assembly,
[12] Ganesan, P. V.; Kepert, C. J. Chem. Commun. 2004, 2168.
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[14] Zhang, J.-P.; Horike, S.; Kitagawa, S. Angew. Chem., Int. Ed. 2007,
6, 889.
[
2
the anions have also participated in the framework con-
struction. The monodentate NO and the bidentate
3
4
2
SO4 have created single Cu ions and dinuclear Zn
clusters as inorganic SBUs for the MOFs, respectively,
due to the metal-inorganic anion coordination. What is
more, the anions are also involved in the hydrogen
bonds between the anions and the organic linkers, re-
sulting in the endo-conformation of the linkers in the
MOF structures. These interactions, combined with the
major metal-ligand coordination, will produce interest-
ing MOFs with more structural diversity and extraordi-
nary properties in the future.
[
[
15] Zhang, J.-P.; Kitagawa, S. J. Am. Chem. Soc. 2008, 130, 907.
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613.
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Acknowledgement
This work was supported by the Education Depart-
ment of Zhejiang (No. Y201120341).
[23] Tǎbǎcaru, A.; Pettinari, C.; Timokhin, I.; Marchetti, F.; Casrras-
co-Maŕin, F.; Maldonado-Hódar, F. J.; Galli, S.; Masciocchi, N.
Cryst. Growth Des. 2013, 13, 3087.
[
[
[
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24] Han, L.-L.; Zhang, X.-Y.; Chen, J.-S.; Li, Z.-H.; Sun, D.-F.; Wang,
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Chin. J. Chem. 2016, 34, 191—195
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