Paper
NJC
16 N. Yadav, F. Seidi, D. Crespy and V. D’Elia, ChemSusChem,
2019, 12, 724–754.
17 M. Li, S. Abdolmohammadi, M. S. Hoseininezhad-Namin,
F. Behmagham and E. Vessally, J. CO2 Util., 2020, 38,
220–231.
propargyl alcohols. A comparative study has highlighted that
[Ag(O2CNEt2)] is more active compared to its commercial
synthetic precursor, i.e. Ag2O, at the same silver concentration.
The promising catalytic activity of the silver carbamate seems
ascribable to the multitasking role of the ligand. DFT calcula-
tions support, on thermodynamic grounds, the viability of
dynamic incorporation of carbon dioxide within the carbamate,
providing the {COO} fragment to the organic product. This
work confirms the interesting potential of metal carbamates,
which constitute a form of pre-activated carbon dioxide, in
promoting CO2-fixation reactions in mild conditions, and
encourages further studies in this direction.
18 B. Grignard, C. Ngassamtounzoua, S. Gennen, B. Gilbert,
´
R. Mereau, C. Jerome, T. Tassaing and C. Detrembleur,
ChemCatChem, 2018, 10, 2584–2592.
´
19 R. Mereau, B. Grignard, A. Boyaval, C. Detrembleur,
C. Jerome and T. Tassaing, ChemCatChem, 2018, 10,
956–960.
20 H. Zhou, G.-X. Wang and X.-B. Lu, Asian J. Org. Chem., 2017,
6, 1264–1269.
21 N. Della, Ca’, B. Gabriele, G. Ruffolo, L. Veltri, T. Zanetta
and M. Costa, Adv. Synth. Catal., 2011, 353, 133–146.
22 U. C. Rajesh, Y. Losovyj, C.-H. Chen and J. M. Zaleski, ACS
Catal., 2020, 10, 3349–3359.
Conflicts of interest
There are no conflicts to declare.
23 P. Sivaguru, S. Cao, K. R. Babu and X. Bi, Acc. Chem. Res.,
2020, 53, 662–675.
24 Y. Hu, J. Song, C. Xie, H. Wu, T. Jiang, G. Yang and B. Han,
ACS Sustainable Chem. Eng., 2019, 7, 5614–5619.
25 J. Hu, J. Ma, Q. Zhu, Q. Qian, H. Han, Q. Mei and B. Han,
Green Chem., 2016, 18, 382–385.
26 Y. Gu, F. Shi and Y. Deng, J. Org. Chem., 2004, 69, 391–394.
27 S. Sun, B. Wang, N. Gu, J. T. Yu and J. Cheng, Org. Lett.,
2017, 19, 1088–1091.
Acknowledgements
The University of Pisa is acknowledged for funding (PRA_2020_39).
References
1 Q. Liu, L. Wu, R. Jackstell and M. Beller, Nat. Commun.,
2015, 6, 1–15.
28 S. S. Islam, N. Salam, R. A. Molla, S. Riyajuddin, N. Yasmin,
D. Das, K. Ghosh and S. M. Islam, Mol. Catal., 2019,
477, 110541.
2 T. Niemi and T. Repo, Eur. J. Org. Chem., 2019, 1180–1188.
3 A. Cherubini-Celli, J. Mateos, M. Bonchio, L. Dell’Amico and
´
X. Companyo, ChemSusChem, 2018, 11, 3056–3070.
29 J. Li, Q. Song, H. Zhang, P. Liu, K. Zhang, J. Wang and
D. Zhang, Tetrahedron, 2019, 75, 2343–2349.
30 S. Dabral, B. Bayarmagnai, M. Hermsen, J. Schießl,
V. Mormul, A. S. K. Hashmi and T. Schaub, Org. Lett.,
2019, 21, 1422–1425.
4 J. Artz, T. E. Mu¨ller, K. Thenert, J. Kleinekorte, R. Meys,
A. Sternberg, A. Bardow and W. Leitner, Chem. Rev., 2018,
118, 434–504.
5 R. R. Shaikh, S. Pornpraprom and V. D. Elia, ACS Catal.,
2018, 8, 419–450.
31 J.-Y. Li, L.-H. Han, Q.-C. Xu, Q.-W. Song, P. Liu and
K. Zhang, ACS Sustainable Chem. Eng., 2019, 7, 3378–3388.
32 Y. Yuan, Y. Xie, D. Song, C. Zeng, S. Chaemchuen, C. Chen
and F. Verpoort, Appl. Organomet. Chem., 2017, 31, e3867.
33 Q.-W. Song, W.-Q. Chen, R. Ma, A. Yu, Q.-Y. Li, Y. Chang and
L.-N. He, ChemSusChem, 2015, 8, 821–827.
6 A. J. Kamphuis, F. Picchioni and P. P. Pescarmona, Green
Chem., 2019, 21, 406–448.
7 S. Wang and C. Xi, Chem. Soc. Rev., 2019, 48, 382–404.
8 R. Dalpozzo, N. Della Ca’, B. Gabriele and R. Mancuso,
Catalysts, 2019, 9, 511.
´
´
9 R. Martin, A. Tortajada, F. Julia-Hernandez, M. Borjesson
and T. Moragas, Angew. Chem., Int. Ed., 2018, 57,
5948–15982.
34 K. Sekine and T. Yamada, Chem. Soc. Rev., 2016, 45,
4524–4532.
35 G. Zhang, H. Yang and H. Fei, ACS Catal., 2018, 8,
2519–2525.
10 N. Kindermann, T. Jose and A. W. Kleij, Top. Curr. Chem.,
2017, 375, 15.
36 J. Qiu, Y. Zhao, H. Wang, G. Cui and J. Wang, RSC Adv.,
2016, 6, 54020–54026.
11 S. L. Hou, J. Dong, X. L. Jiang, Z. H. Jiao and B. Zhao, Angew.
Chem., Int. Ed., 2019, 58, 577–581.
37 M. Cui, Q. Qian, Z. He, J. Ma, X. Kang, J. Hu, Z. Liu and
B. Han, Chem. – Eur. J, 2015, 21, 15924–15928.
38 Y. Yuan, Y. Xie, C. Zeng, D. Song, S. Chaemchuen, C. Chen
and F. Verpoort, Green Chem., 2017, 19, 2936–2940.
39 K. Chen, G. Shi, R. Dao, K. Mei, X. Zhou, H. Li and C. Wang,
Chem. Commun., 2016, 52, 7830–7833.
40 Q.-W. Song, B. Yu, X.-D. Li, R. Ma, Z.-F. Diao, R.-G. Li, W. Li
and L.-N. He, Green Chem., 2014, 16, 1633–1638.
41 G. Bresciani, L. Biancalana, G. Pampaloni and F. Marchetti,
Molecules, 2020, 25, 3603.
12 R. Ninokata, T. Yamahira, G. Onodera and M. Kimura,
Angew. Chem., Int. Ed., 2017, 56, 208–211.
13 H. Zhang, H.-B. Liu and J.-M. Yue, Chem. Rev., 2014, 114,
883–898.
14 F. Ouhib, B. Grignard, E. Van Den Broeck, A. Luxen,
K. Robeyns, V. Van Speybroeck, C. Jerome and
C. Detrembleur, Angew. Chem., Int. Ed., 2019, 58,
11768–11773.
´ ˆ
15 B. Grignard, S. Gennen, C. Jerome, A. W. Kleij and
C. Detrembleur, Chem. Soc. Rev., 2019, 48, 4466–4514.
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