Journal of Organometallic Chemistry p. C77 - C88 (1984)
Update date:2022-08-11
Topics:
Behr, Arno
Ilsemann, Godard von
Reaction of equimolar amounts of μ-1-3-η:6-8-η-octadienatobis(1,1,1,5,5,5-hexafluoroacetylacetonatopalladium) and triisopropylphosphine gives a bimetalic octadienyl-bridged complex, in which one palladium atom is η1-bound to the terminal carbon of the octadienyl chain.Insertion of CO2 into this Pd-C bond gives a carboxylate complex; acidic decomposition and hydrogenation of the carboxylate complex gives pelargonic acid.The results are discussed in relation to the mechanism of the palladium-catalyzed reaction between butadiene and carbon dioxide.
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