Polyhedron p. 197 - 201 (2015)
Update date:2022-08-16
Topics:
Ourari, Ali
Messali, Salima
Bouzerafa, Brahim
Ouennoughi, Yasmina
Aggoun, Djouhra
Mubarak, Mohammad S.
Strawsine, Lauren M.
Peters, Dennis G.
A new tetradentate cobalt(II)-Schiff base complex has been synthesized via the reaction of the ligand 2,2′-((1E,1′E)-(ethane-1,2-diylbis(azanylylidene))bis(ethan-1-yl-1-ylidene))bis(4-((methyl(phenyl)amino)methyl)phenol) with a stoichiometric amount of cobalt(II) acetate tetrahydrate in absolute ethanol. This cobalt(II) complex has been characterized with the aid of several spectroscopic techniques (FT-IR, UV-Vis, and mass spectrometry) as well as by thermal (TGA and DTA) and elemental analysis. Cyclic voltammetry has been employed to examine the redox behavior of the cobalt(II) complex in dimethylformamide (DMF) containing 0.10 M tetra-n-butylammonium tetrafluoroborate (TBABF4). In addition, the electrogenerated cobalt(I) form of the complex has been (a) employed as a catalyst for the reduction of 1-iododecane and (b) compared with the behavior of cobalt(I) salen. Finally, the cobalt(II) complex has been subjected to anodic electropolymerization onto the surface of a glassy carbon electrode in DMF containing 0.10 M tetra-n-butylammonium perchlorate (TBAP).
View MoreJiangxi Dongbang Pharmaceutical Co., Ltd.
Contact:+86-795-4433603, 4433388
Address:Fengxin Industrial Park, Fengxin County, Jiangxi Province, P.R.C
Weifang Yukai Chemical Co.,Ltd.
website:http://www.yukaichem.com/en.html
Contact:+86-536-8865336
Address:binhai economic development zone,262737 shangdong,china
Contact:86-931-8272767
Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC
Guangxi Shanyun Biochemical Science and Technology Co., Ltd
Contact:+86-0772--6828887
Address:#2 Industrial Park of Luzhai County, Liuzhou, Guangxi, China
Xi'an Kaixiang Photoelectric Technology Co., Ltd
website:http://www.kxmaterials.com/
Contact:86-29-15991651477
Address:Building 6, Biopharmaceutical Industry R&D Cluster Base, No. 16, Caotang 4th Road, Caotang Science and Technology Industrial Base, High-tech Zone, Xi'an City, Shaanxi Province, China
Doi:10.1021/ol026317g
(2002)Doi:10.1021/ac50107a015
(1937)Doi:10.1002/cctc.202100054
(2021)Doi:10.1007/BF00778453
()Doi:10.1039/DT9870001611
(1987)Doi:10.1021/jacs.7b02911
(2017)