Journal of Organic Chemistry p. 3227 - 3229 (1980)
Update date:2022-08-16
Topics:
Savoia, Diego
Tagliavini, Emilio
Trombini, Claudio
Umani-Ronchi, Achille
Highly dispersed potassium over neutral alumina (K/Al2O3), easily prepared by melting potassium over alumina in an inert atmosphere, is capable of effecting reductive cleavage of the cyano group in alkylnitriles in hexane at room temperature in 70-91percent yield.This decyanation method is applied in the key step of a novel synthesis of (Z)-9-dodecen-1-yl acetate, the sex pheromone of Paralobesia viteana.
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