RSC Advances
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responsible for the higher catalytic activity of the Pd0.5–Ru0.5 11 M. M. Dell'Anna, V. F. Capodiferro, M. Mali, D. Manno,
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In summary, we have developed a successful example of
Pd0.5–Ru0.5 NPs for the hydrogenation of N-,O-heteroarenes and 12 L. Bai, X. Wang, Q. Chen, Y. Ye, H. Zheng, J. Guo, Y. Yin and
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catalyst which was extensively studied for the hydrogenation of 13 G.-Y. Fan and J. Wu, Catal. Commun., 2013, 31, 81.
quinoline. A parametric study demonstrated that methanol was 14 H. Mao, X. Liao and B. Shi, Catal. Commun., 2011, 16, 210.
the best solvent for the hydrogenation of heteroarenes, whereas 15 H.-Y. Jiang and X.-X. Zheng, Appl. Catal., A, 2015, 499, 118.
solvent-free conditions facilitated for the hydrogenation of 16 M. Niu, Y. Wang, P. Chen, D. Du, J. Jiang and Z. Jin, Catal.
arenes. The catalyst was recycled three times recycled without
loss in activity. It is likely that Pd0.5–Ru0.5 NPs could be efficient 17 A. Karakulina, A. Gopakumar, I. Akçok, B. L. Roulier,
Sci. Technol., 2015, 5, 4746.
˙
catalysts for the hydrogenation of nitroarenes and synthesis of
N-heterocycles. Currently, we are exploring this possibility.
T. LaGrange, S. A. Katsyuba, S. Das and P. J. Dyson, Angew.
Chem., 2016, 128, 300.
18 M. N. Shaikh, Md. A. Aziz, A. N. Kalanthoden, A. Helal,
A. S. Hakeem and M. Bououdinac, Catal. Sci. Technol.,
Author contributions
2018, 8, 4709.
Chandan Chaudhari: designing of research, data collection, 19 F. Martinez-Espinar, P. Blondeau, P. Nolis, B. Chaudret,
analysis and writing-editing. Katsutoshi Sato: data curation and
validation. Yoshihide Nishida: data collection. Katsutoshi
C. Claver, S. Castill ´o n and C. Godard, J. Catal., 2017, 354,
113.
Nagaoka: designing of research, data collection, analysis and 20 A. Karakulina, A. Gopakumar, Z. Fei and P. J. Dyson, Catal.
writing-editing. Yasuyuki Ikeda, Kenji Terada and Naoya Abe: Sci. Technol., 2018, 8, 5091.
catalyst preparation. Tomokazu Yamamoto, Takaaki Toriyama 21 Z. Luo, Y. Min, D. Nechiyil, W. Bacsa, Y. Tison, H. Martinez,
and Syo Matsumura: HAADF-STEM analysis. Kohei Kusuda and
Hiroshi Kitagawa: XPS analysis and catalyst design.
P. Lecante, I. C. Gerber, P. Serpa and M. R. Axet, Catal. Sci.
Technol., 2019, 9, 6884.
2
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2 I. S. Park, M. S. Kwon, K. Y. Kang, J. S. Lee and J. Park, Adv.
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Conflicts of interest
There are no conicts to declare.
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Acknowledgements
5 N. Zarkevich, T. Tan and D. Johnson, Phys. Rev. B, 2007, 75,
This research was supported by the ACCEL program, Japan
Science and Technology Agency (JST), JPMJAC1501.
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7 K. Kusada, H. Kobayashi, R. Ikeda, Y. Kubota, M. Takata,
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