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ChemComm
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DOI: 10.1039/C8CC03806F
COMMUNICATION
Journal Name
captured by benzyne generated in situ to accomplish the final
product 3aa.
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1
In summary, we have reported
a tandem nucleophilic
addition/cycloaddition reaction for the synthesis of functionalized
imidazolidine derivatives. This asymmetric tandem transformation
afforded imidazolidine derivatives with high yields, excellent regio-,
diastereo-, and enantioselectivities. A variety of α-iminoesters and
aryne precursors were well tolerated under the present reaction
conditions. The [3+2] cycloaddition of aryne-induced ylides with
metalated α-iminoesters and metal-catalyzed [3+2] cycloaddition of
azomethine ylide with α-iminoesters are two concurrent pathways
to imidazolidines.
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