Tetrahedron Asymmetry p. 1970 - 1972 (2008)
Update date:2022-08-11
Topics:
Dabiri, Minoo
Salehi, Peyman
Kozehgary, Gholamreza
Heydari, Seddigheh
Heydari, Akbar
Esfandyari, Maryam
Enantioselective addition reactions of diethylzinc to aromatic aldehydes were performed with catalytic amounts of 14-hydroxylsubstituted morphine alkaloids. The reaction conditions such as catalyst loading, time and temperature were optimized to obtain the highest enantiomeric excess. Optically active secondary alcohols were synthesized with ee up to 95%.
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Doi:10.1016/S0040-4039(00)92194-4
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