Chemistry of Heterocyclic Compounds p. 266 - 270 (1987)
Update date:2022-08-11
Topics:
Daukshas, V. K.
Pyatrauskas, O. Yu.
Purvanyatskas, G. N.
The isomeric compositions of the products of nitration of 2-methylcoumaran and chroman with acetyl nitrate were determined.More convenient methods for the synhtesis of 7-amino-2-methylcoumaran and 8-aminochroman were developed, and 9-amino-1-benzoxepane was obtained for the first time.Alkylaminoacylaminosubstituted 2-methylcoumarans, chromans, and 1-benzoxepanes were synthesized.A method for the synthesis of 2-bromocaproyl chloride from caproic acid was developed.
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