Journal of Fluorine Chemistry p. 165 - 177 (1992)
Update date:2022-08-15
Topics:
Bardin, V.V.
Rogoza, L.N.
Stennikova, I.V.
Furin, G.G.
This paper reports the results of studies on the reactions of trialkylsilyl-and germylpentafluorobenzenes with O-,N,- S- and C-nucleophiles, and with LiAlH4.Depending on the nature of the nucleophilic reagent, its attack is oriented towards a heteroatom (RO-,RS-), the C-4 atom of the pentafluorophenyl ring (BuLi, LiAlH4, piperidyl-lithium) or at both electrophilic centres (piperidine, RS-.
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