Chemical and Pharmaceutical Bulletin p. 430 - 437 (1994)
Update date:2022-08-30
Topics:
Takeya
Ohguchi
Ara
Tobinaga
Several (±)-dibenzocyclooctadiene lignans, (±)-schizandrin (1a) (±)- gomisin A (1b), and their stereoisomers 2a and 2b, were synthesized by the samarium-Grignard reaction of the phenylpropyl bromides 4 and the phenylacetone derivative 5 to give the erythro and threo-butanols 6 and 7 followed by oxidative aryl-aryl coupling reaction of each butanol.
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