Chemistry Letters p. 1051 - 1052 (1995)
Update date:2022-08-15
Topics:
Kunai, Atsutaka
Ohnishi, Osamu
Sakurai, Tomohiro
Ishikawa, Mitsuo
Electrolysis of iodosilanes with Al/Pt electrodes in pivalonitrile results in the formation of the Si-Si bonds to give the corresponding disilanes.On the other hand, the electrolysis of various halosilanes such iodo-, chloro-, and fluorosilanes with Pt/Pt electrodes in the presence of phenylacetylene leads to the formation of the Si-sp-carbon bonds to give phenylethynylated products.
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