Journal of Physical Chemistry p. 5873 - 5875 (1987)
Update date:2022-08-11
Topics:
Chettur, G.
Snelson, A.
tert-Butyl radicals formed by the pyrolysis of azoisobutane were isolated in matrices of Ar + 10percent 16O2 and Ar + 5percent 16O2 + 5percent 18O2.IR spectra of the resulting trapped species were obtained before and after irradiation of the matrices with a medium-pressure Hg arc lamp.In the 1200-200-cm-1 spectral range, nine absorption bands were observed and assigned to the tert-butylperoxy radical.A summary of the known vibration frequencies assigned to primary, secondary, and tertiary alkylperoxy radical centers is presented.
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