Bulletin of the Chemical Society of Japan p. 3448 - 3452 (1985)
Update date:2022-08-16
Topics:
Sawada, Hideo
Hagii, Hidehiko
Aoshima, Kazuyoshi
Yoshida, Masato
Kobayashi, Michio
Kinetical studies and products analyses of the thermal decomposition of t-butyl heptafluoroperoxybutyrate (TBH) in benzene, octane, nitrobenzene, pyridine, and methoxybenzene have been carried out.In benzene and octane, the decoposition appears to be entirely a radical process.In nitrobenzene and pyridine, the reactions are found to give ionic decomposition proudcts exclusively.On the other hand, the decomposition of TBH in methoxybenzene is characteristic of mixed ionic and radical cleavages.
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