Chemistry Letters p. 2153 - 2156 (1984)
Update date:2022-08-28
Topics:
IRIE, Setsuko
A selective formose synthesis was achieved by photo- and γ-irradiation of formaldehyde in the presence of base.Photoirradiation of aqueous formaldehyde solution gave pentaerythritol as a single product, while γ-irradiation resulted in the formation of glycolaldehyde as the main product.These results suggest that the formose reaction under photo- and γ-irradiation is considerably different from the thermal formose reaction.
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