Journal of Molecular Structure p. 533 - 536 (1986)
Update date:2022-08-11
Topics:
Santos, M.
Hernandez-Vara, R.
Herreros, J. M.
Gonzales-Diaz, P. F.
The dissociation products of CF2Cl2 irradiated in the line P20 at 9.17 μm with pulses of fluence as high as 60E4 J*m-2 depend on the pressure of the gas, giving rise to C2F4 only when the pressure is of the order of 2 mb.At remarkably lower fluence (2E4 J*m-2) this product appears however in a wide range of pressures. For CF2HCl, C2F4 is the only product that appears at fluences as high as 60E4 J*m-2).At lower fluences (2.5E4 J*m-2), less C2F4 is produced and another product, probably a halogenated derivative of butane, is obtained.
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