Chemical Physics Letters p. 36 - 40 (2006)
Update date:2022-08-25
Topics:
Isosomppi, Marja
Tkachenko, Nikolai V.
Efimov, Alexander
Vahasalo, Heidi
Jukola, Johanna
Vainiotalo, Pirjo
Lemmetyinen, Helge
Three new double-bridged phthalocyanine-fullerene dyads were studied with spectroscopic and electrochemical methods. The two-linker strategy was applied for the first time to phthalocyanine-fullerene dyads. Photoinduced electron transfer (ET) of the dyads was found to occur from the excited state of phthalocyanine both in polar and non-polar environment. Examination of ET energetics revealed that the phthalocyanine-fullerene dyads exist mainly in an extended conformation as opposed to a face-to-face orientation common for the similar double-bridged porphyrin-fullerene dyads.
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