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New Journal of Chemistry
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Journal Name
ARTICLE
Microscopy
2002, 41, 1290-1309.
DOI: 10.1039/C5NJ03337C
24 A. Cervilla, F. Pérez-Pla, E. Llopis and M. Piles, Inorganic
Chemistry, 2006, 45, 7357-7366.
General procedure for TEM analysis
25 F. Godoy, C. Segarra, M. Poyatos and E. Peris,
Organometallics, 2011, 30, 684-688.
26 C.-C. Yang, P.-S. Lin, F.-C. Liu, I. J. B. Lin, G.-H. Lee and S.-M.
Peng, Organometallics, 2010, 29, 5959-5971.
27 F. Churruca, R. SanMartin, B. Inés, I. Tellitu and E.
The samples were prepared by pipetting a drop of solution or
dispersion onto copper plates coated in a carbon film. The
precipitate sample was prepared by dispersing the centrifuged
and washed solid in chloroform. The nanoparticle colloidal
solution in water was prepared by dissolving 5b in water with
K2CO3 and TBAB.
Domínguez, Advanced Synthesis & Catalysis, 2006, 348
,
1836-1840.
28 B. Inés, R. SanMartin, M. J. Moure and E. Domínguez,
Advanced Synthesis & Catalysis, 2009, 351, 2124-2132.
29 T. Tu, X. Feng, Z. Wang and X. Liu, Dalton Transactions, 2010,
39, 10598-10600.
30 H. Turkmen, R. Can and B. Cetinkaya, Dalton Transactions,
2009, 7039-7044.
Acknowledgements
The authors would like to thank the Max-Planck Society for
financial support of this work.
31 L. Benhamou, E. Chardon, G. Lavigne, S. Bellemin-Laponnaz
and V. César, Chemical Reviews, 2011, 111, 2705-2733.
32 D. Esposito, S. Kirchhecker and M. Antonietti, Chemistry – A
European Journal, 2013, 19, 15097-15100.
33 K. Täuber, Q. Zhao, M. Antonietti and J. Yuan, ACS Macro
Notes and references
Letters, 2015, 4, 39-42.
34 J. DePasquale, N. J. White, E. J. Ennis, M. Zeller, J. P. Foley
and E. T. Papish, Polyhedron, 2013, 58, 162-170.
1
2
P. Pollet, E. A. Davey, E. E. Urena-Benavides, C. A. Eckert and
35 M. A. Reynoso-Esparza, I. I. Rangel-Salas, A. A. Peregrina-
Lucano, J. G. Alvarado-Rodríguez, F. A. López-Dellamary-
Toral, R. Manríquez-González, M. L. Espinosa-Macías and S.
A. Cortes-Llamas, Polyhedron, 2014, 81, 564-571.
36 M. Pellei, V. Gandin, M. Marinelli, C. Marzano, M.
Yousufuddin, H. V. R. Dias and C. Santini, Inorganic
Chemistry, 2012, 51, 9873-9882.
37 C. J. O'Brien, E. A. B. Kantchev, C. Valente, N. Hadei, G. A.
Chass, A. Lough, A. C. Hopkinson and M. G. Organ, Chemistry
– A European Journal, 2006, 12, 4743-4748.
38 § Crystal data of 4a. C22H32Cl2N4O8Pd. M = 657.81 g•mol-
1, monoclinic, a = 12.2261(3), b = 27.7257(6), c = 17.0282(4)
Å, β = 99.793(2)°, V = 5688.1(2) Å3, T = 210 K, space group
P21/n, (no. 14), Z = 8, 69663 reflections measured, 9541
unique, (Rint = 0.0616), which were used in all calculations.
The final wR(F2) was 0.0978 (all data). CCDC-1438609
C. L. Liotta, Green Chemistry, 2014, 16, 1034-1055.
M.-O. Simon and C.-J. Li, Chemical Society Reviews, 2012, 41
1415-1427.
T. Welton, Chemical Reviews, 1999, 99, 2071-2084.
,
3
4
S. Kirchhecker, M. Antonietti and D. Esposito, Green
Chemistry, 2014, 16, 3705-3709.
5
6
7
V. Pace, P. Hoyos, L. Castoldi, P. Domínguez de María and A.
R. Alcántara, ChemSusChem, 2012, 5, 1369-1379.
V. Molinari, M. Antonietti and D. Esposito, Catalysis Science
& Technology, 2014, 4, 3626-3630.
P. Tundo, P. Anastas, D. Black, J. Breen, T. Collins, S. Memoli,
J. Miyamoto, M.Polyakoff, and W. Tumas Pure Appl. Chem,
2000, 72, 1207–1228.
8
9
M. B. Gawande, V. D. B. Bonifacio, R. Luque, P. S. Branco and
R. S. Varma, Chemical Society Reviews, 2013, 42, 5522-5551.
K. H. Shaughnessy, Chemical Reviews, 2009, 109, 643-710.
39 §§ Crystal data of 4b. C26H40Cl2N4O8Pd. M = 713.29 g•mol-
1, monoclinic, a = 10.3920(5), b = 12.0677(7), c = 25.5618(10)
Å, β = 98.377(3)°, V = 3171.4(3) Å3, T = 210 K, space group
C2/c, (no. 15), Z = 4, 10088 reflections measured, 2804
unique, (Rint = 0.0178), which were used in all calculations.
The final wR(F2) was 0.0610 (all data). CCDC-1438610
10 L.-A. Schaper, S. J. Hock, W. A. Herrmann and F. E. Kühn,
Angewandte Chemie International Edition, 2013, 52, 270-
289.
11 A. Azua, S. Sanz and E. Peris, Organometallics, 2010, 29
,
3661-3664.
12 H. Horváth, Á. Kathó, A. Udvardy, G. Papp, D. Szikszai and F.
Joó, Organometallics, 2014, 33, 6330-6340.
13 V. Pénicaud, C. Maillet, P. Janvier, M. Pipelier and B. Bujoli,
European Journal of Organic Chemistry, 1999, 1745-1748.
14 J. Tomasek and J. Schatz, Green Chemistry, 2013, 15, 2317-
2338.
15 B. Mohr, D. M. Lynn and R. H. Grubbs, Organometallics,
1996, 15, 4317-4325.
16 A. L. Casalnuovo and J. C. Calabrese, Journal of the American
Chemical Society, 1990, 112, 4324-4330.
17 R. Zhong, A. Pothig, Y. Feng, K. Riener, W. A. Herrmann and
F. E. Kühn, Green Chemistry, 2014, 16, 4955-4962.
18 L. Li, J. Wang, C. Zhou, R. Wang and M. Hong, Green
Chemistry, 2011, 13, 2071-2077.
19 E. Levin, E. Ivry, C. E. Diesendruck and N. G. Lemcoff,
Chemical Reviews, 2015, 115, 4607-4692.
20 H. D. Velazquez and F. Verpoort, Chemical Society Reviews,
2012, 41, 7032-7060.
21 D. Bourissou, O. Guerret, F. P. Gabbaï and G. Bertrand,
Chemical Reviews, 1999, 100, 39-92.
40 §§§ Crystal data of 5a•CHCl3. C17H22Cl5N3O4Pd. M =
616.02 g•mol-1, monoclinic, a = 11.7256(4), b = 23.0938(8), c
= 9.0944(6) Å, V = 2428.7(2) Å3, T = 210 K, space group
P21/c, (no. 14), Z = 4, 15567 reflections measured, 4269
unique, (Rint = 0.0364), which were used in all calculations.
The final wR(F2) was 0.0613 (all data). CCDC- 1438611.
41 §§§§ Crystal data of 5b. C18H25Cl2N3O4Pd. M = 524.71
g•mol-1, triclinic,
a = 9.4985(8), b = 9.7104(7), c =
12.2951(10) Å, V = 1111.72(15) Å3, T = 210 K, space group
P¯1, (no. 2), Z = 2, 14413 reflections measured, 3924 unique,
(Rint = 0.0243), which were used in all calculations. The final
wR(F2) was 0.0533 (all data). CCDC-1438612
42 H. Lebel, M. K. Janes, A. B. Charette and S. P. Nolan, Journal
of the American Chemical Society, 2004, 126, 5046-5047.
43 W. A. Herrmann, L. J. Gooβen and M. Spiegler, Journal of
Organometallic Chemistry, 1997, 547, 357-366.
44 P. Lara, O. Rivada-Wheelaghan, S. Conejero, R. Poteau, K.
Philippot and B. Chaudret, Angewandte Chemie International
Edition, 2011, 50, 12080-12084.
45 A. Ferry, K. Schaepe, P. Tegeder, C. Richter, K. M. Chepiga, B.
J. Ravoo and F. Glorius, ACS Catalysis, 2015, 5414-5420.
22 G. C. Fortman and S. P. Nolan, Chemical Society Reviews,
2011, 40, 5151-5169.
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