Inorganica Chimica Acta (2020)
Update date:2022-08-17
Topics:
Liu, Wei-Xia
Xie, Zhen-Lang
Zhan, Jun-Zheng
Zhan, Shu-Zhong
Wu, Song-Ping
S,S′-bis(2-pyridylmethyl)-1,2-thiobenzene (bptb) reacts with CoBr2 to form a cobalt complex, [(bptb)CoBr2]. Its structure has been determined by X-ray crystallography. Studies show that [(bptb)CoBr2] can act as both a single-molecule magnet and a molecular catalyst. As a single-molecule magnet, magnetic anisotropy for [(bptb)CoBr2] is revealed via the analyses of the direct-current magnetic data with a zero-field splitting (ZFS) parameter (D) of 69.88 cm?1. Catalytic activities for hydrogen evolution from water are found. As an electrocatalyst, [(bptb)CoBr2] can provide 870 mol of hydrogen per mole of catalyst per hour (mol H2/mol catalyst/h) at an overpotential (OP) of 837.6 mV. As a photocatalyst, mixing with CdS nanorods (CdS NRs) as a photosensitizer, and ascorbic acid (H2A) as a sacrificial electron donor, [(bptb)CoBr2] can afford 19290 mol H2 per mole of catalyst during 80 h irradiation. The highest apparent quantum yield (AQY) is ~24.30%.
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Doi:10.1002/anie.201302818
(2013)Doi:10.1021/acs.cgd.5b00086
(2015)Doi:10.1021/jo00964a002
(1973)Doi:10.1016/0584-8539(71)80088-0
(1971)Doi:10.4067/S0717-97072010000200003
(2010)Doi:10.1515/hc-2015-0141
(2015)