Tetrahedron Letters p. 4875 - 4878 (1991)
Update date:2022-08-28
Topics:
McNulty
Still
The carbon skeleton present in eudistomins H, I and woodinine may be envisioned to be biosynthetically derived from tryptamine and L-prolinal by a Pictet-Spengler type reaction. The diastereoselectivity (> 5:1) of this reaction, and the elaboration of the Pictet-Spengler products into the title compounds is described. The absolute stereochemistry of (-) woodinine is thereby established.
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