Journal of Physical Chemistry p. 4978 - 4981 (1983)
Update date:2022-08-29
Topics:
Niki, H.
Maker, P. D.
Savage, C. M.
Breitenbach, L. P.
Gaseous and aerosol products formed in the HO-radical initiated reaction of CH3HgCH3 were studied by the long-path FT IR method in the photolysis of CH3HgCH3-C2H5ONO-NO mixtures typically at 10, 10, and 20 ppm each in 700 torr of air at ca. 300 K.The results were consistent with the predominant occurence of the displacement reaction of HO + CH3HgCH3 -> CH3HgOH + CH3 as the primary process.The relative rate constant for the HO-radical reactions of CH3HgCH3 and C2H4 was determined to be k(C3H4)/k(CH3HgCH3) = 0.43 +/- 0.03(?).This value combined with the literature value of k(C2H4) = (8.48 +/- 0.39) X 10-12 cm3 molecule-1 s-1.
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Doi:10.1039/f19837902389
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