Synthetic Communications p. 2051 - 2059 (1995)
Update date:2022-08-12
Topics:
Mohand
Levina
Muzart
The course and the efficacy of the oxidation by sodium percarbonate of benzylic alcohols, α-substituted by a keto, hydroxy, ester or acid group, are dependent on the nature of both α-group and the solvent, and yields are usually improved by the presence of catalytic amounts of Cr(VI) species. The oxidative cleavage of the C(OH)-C(α) bond is the main process observed.
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