Tetrahedron p. 8111 - 8118 (1991)
Update date:2022-08-29
Topics:
Kishi
Mikami
Nakai
Intramolecular acylations of m-trimethylsilyl-m-alkenoyl chlorides (m = 4 and 5) are described which afford the expected α-alkylidenecycloalkanone and/or the unexpected cycloalkenone, depending markeldy upon the substitution pattern on the vinylsilane moiety and/or the chain length (m).
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