Synthetic Communications p. 3947 - 3952 (2003)
Update date:2022-08-11
Topics:
Yuasa, Yoshifumi
Shibuya, Shiroshi
Yuasa, Yoko
Methyleugenol 1a was oxidized to give 3,4-dimethoxyphenylacetaldehyde by the oxidative system containing the RuCl3-NaIO4-phase transfer catalyst. The yield and spectroscopic properties were obtained from the stable acetaldoxim 3a. Furthermore, this oxidation system could be applied to other arylpropenes, thus, safrole, 4-methoxyallylbenzene, allylbenzene, and the corresponding arylacetaldehyde formed.
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