Advanced Synthesis & Catalysis
10.1002/adsc.201901223
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Scheme 4. Proposed Mechanism
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[
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To a 10 mL dried schlenk tube was added acid fluoride
(
3 3 2
0.2 mmol), Me SnSnMe (0.3 mmol), PdCl (0.02 mmol)
2
and dcypb (0.024 mmol). The schlenk tube was then
evacuated and back-filled with argon, that was repeated for
several times. Subsequently, dry o-Xylene (1.0 ml) was
added via syring. The mixture was stirred for 10 h at 140
2
5
o
C, and the reaction solution was extracted with ethyl
acetate, The organic phase was washed with brine and
dried over Na SO , then concentrated in vacuum. The
2 4
residue was purified on column chromatography or
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1
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This work was supported by grants (to D.-Y. Wang. and A.
Zhang.) from the National Natural Science Foundation of China
(
81773565, 21702216, 81430080), the National Program on Key
Basic Research Project (973 Program) of China
2015CB910603), the Shanghai Commission of Science and
(
1
6477–16480; c) M. M. Logan, T. Toma, R. Thomas-
Technology (14431905300, 14431900400), Special research
assistant grant program, Chinese Academy of Sciences, as well
as the National Science & Technology Major Project “Key New
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