Phosphorus, Sulfur and Silicon and the Related Elements p. 2063 - 2078 (2006)
Update date:2022-08-10
Topics:
Zuev, Vjacheslav
De Vekki, Dimitry
In the present article, we report on the synthesis and investigation of the hydrosilylation of liquid crystalline compounds with terminal carbon-carbon double bonds in aliphatic tails mediated by complexes of rhodium (I) and platinum (II). New liquid crystalline compounds based on terephthaloyl-bis-4- oxybenzoate with terminal carbon-carbon double bonds in aliphatic tails were synthesized. The introduction in aliphatic tails of polar and light polarizible fragments lead to a decrease of mesomorphogenic ability-resulting compounds. The hydrosilylation of liquid crystalline compounds with terminal carbon-carbon double bonds in aliphatic tails with 1-(1′-arylethoxy)-1,1,3,3-tetramethyl disiloxanes mediated by complexes of rhodium (I) and platinum (II) was investigated. The main process in these conditions was the isomerization of olefin fragments. Copyright Taylor & Francis Group, LLC.
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